Kinetics and Mechanism of Hydrolysis of O-Hydroxy Benzaldehyde - Aniline Spectrophotometrically
International Journal of Science and Research (IJSR)

International Journal of Science and Research (IJSR)
Call for Papers | Fully Refereed | Open Access | Double Blind Peer Reviewed

ISSN: 2319-7064


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Research Paper | Chemical Sciences | India | Volume 9 Issue 1, January 2020 | Popularity: 6.1 / 10


     

Kinetics and Mechanism of Hydrolysis of O-Hydroxy Benzaldehyde - Aniline Spectrophotometrically

Anil S. Kirdant, Bhausaheb K. Magar


Abstract: Kinetics of hydrolysis reaction of the Schiff base, Ortho Hydroxy Benzaldehyde - aniline (HL) have been studied in the pH range 2.86-12.30 at temperature range 293-308 K. A rate profile diagram of pH v/s rate constant shows the rate minimum in the pH range 5.21-10.22 and reaches a plateau at pH > 10.73. Suitable reaction mechanism has been suggested for the hydrolysis of the Schiff base in acidic, neutral and basic medium. From the effect of temperature on the rate, various thermodynamic parameters have been evaluated.


Keywords: Schiff base, hydrolysis, kinetics, Spectrophotometry


Edition: Volume 9 Issue 1, January 2020


Pages: 1134 - 1137



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Anil S. Kirdant, Bhausaheb K. Magar, "Kinetics and Mechanism of Hydrolysis of O-Hydroxy Benzaldehyde - Aniline Spectrophotometrically", International Journal of Science and Research (IJSR), Volume 9 Issue 1, January 2020, pp. 1134-1137, https://www.ijsr.net/getabstract.php?paperid=ART20204267, DOI: https://www.doi.org/10.21275/ART20204267

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