Redox Modification of a Ferrocenylimine Ligands for Iron III-CrCl2 Catalysis in Ethylene Polymerization
International Journal of Science and Research (IJSR)

International Journal of Science and Research (IJSR)
Call for Papers | Fully Refereed | Open Access | Double Blind Peer Reviewed

ISSN: 2319-7064


Downloads: 1 | Views: 131 | Weekly Hits: ⮙1 | Monthly Hits: ⮙1

Research Paper | Chemistry | France | Volume 13 Issue 12, December 2024 | Popularity: 4.8 / 10


     

Redox Modification of a Ferrocenylimine Ligands for Iron III-CrCl2 Catalysis in Ethylene Polymerization

Cyril Revault, Audrey Cabrol, Olivier Lavastre


Abstract: This study explores the redox modification of ferrocenylimines using iodine to develop a novel Iron III-CrCl2-based catalyst. This catalyst demonstrates exceptional activity in ethylene polymerization under mild conditions, achieving 2.6 tons of polyethylene per mol of catalyst per hour. Electrochemical studies reveal unexpected modifications to the ligand structure, diverging from simple reversible redox processes. These findings open new avenues for designing advanced polymerization catalysts with enhanced efficiency.


Keywords: ethylene polymerization, redox active ligand, ferrocenylimine, Iron III-CrCl2, catalysis


Edition: Volume 13 Issue 12, December 2024


Pages: 370 - 373


DOI: https://www.doi.org/10.21275/SR241202193104



Make Sure to Disable the Pop-Up Blocker of Web Browser


Text copied to Clipboard!
Cyril Revault, Audrey Cabrol, Olivier Lavastre, "Redox Modification of a Ferrocenylimine Ligands for Iron III-CrCl2 Catalysis in Ethylene Polymerization", International Journal of Science and Research (IJSR), Volume 13 Issue 12, December 2024, pp. 370-373, https://www.ijsr.net/getabstract.php?paperid=SR241202193104, DOI: https://www.doi.org/10.21275/SR241202193104