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Research Paper | Chemistry | India | Volume 3 Issue 5, May 2014

Study of Various Factors on Oxidation of p-Nitro Benzoic Acid Hydrazide - A Kinetic and Mechanistic Approach

A. S. Varale ^[2] | Y. S. Varale ^[2]

Abstract: The kinetics of oxidation of p-nitro benzoic acid hydrazide by Thaliium (III) in a mixture of perchloric and hydrochloric acid medium at a constant ionic strength has been planned to study iodometrically. TlIII + Hydrazide Complex Kc Complex TlI + Intermediate kl TlIII+Intermediate TlI + Products fast The increase in [H+] and [Cl-] decreases the rate of the reaction. The activation parameters were also determined and a mechanism is predicted.

Keywords: Kinetics, Thermodynamics, Thallium III, Oxidation, Hydrazide

Edition: Volume 3 Issue 5, May 2014,

Pages: 1865 - 1867