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India | Chemistry | Volume 3 Issue 5, May 2014 | Pages: 1865 - 1867
Study of Various Factors on Oxidation of p-Nitro Benzoic Acid Hydrazide - A Kinetic and Mechanistic Approach
Abstract: The kinetics of oxidation of p-nitro benzoic acid hydrazide by Thaliium (III) in a mixture of perchloric and hydrochloric acid medium at a constant ionic strength has been planned to study iodometrically. TlIII + Hydrazide Complex Kc Complex TlI + Intermediate kl TlIII+Intermediate TlI + Products fast The increase in [H+] and [Cl-] decreases the rate of the reaction. The activation parameters were also determined and a mechanism is predicted.
Keywords: Kinetics, Thermodynamics, Thallium III, Oxidation, Hydrazide
How to Cite?: A. S. Varale, Y. S. Varale, "Study of Various Factors on Oxidation of p-Nitro Benzoic Acid Hydrazide - A Kinetic and Mechanistic Approach", Volume 3 Issue 5, May 2014, International Journal of Science and Research (IJSR), Pages: 1865-1867, https://www.ijsr.net/getabstract.php?paperid=201446, DOI: https://dx.doi.org/10.21275/201446