International Journal of Science and Research (IJSR)

International Journal of Science and Research (IJSR)
Call for Papers | Fully Refereed | Open Access | Double Blind Peer Reviewed

ISSN: 2319-7064


Downloads: 111

Research Paper | Chemistry | Iraq | Volume 3 Issue 11, November 2014


Synthesis and Characterization of New Complexes of 2- (2-Hydroxy Phenyl)-2-N-Amino (4-Chloro-Benzothiazol-2-Yl) Acetonitrile Ligand with Some Divalent Transition Metal Ions

Mohammed H. A. Al-Amery


Abstract: A series of metal complexes of some divalent transition metal ions [MnII, CoII, NiII, CuII, ZnII, CdII, HgII] having the general composition [ML2Cl2]. nH2O with bidentate 2- (2-hydroxy phenyl) -2-N-amino (4-chloro- benzothiazol-2-yl) acetonitrile ligand which was prepared from 2-hydroxy-benzaldehyde and 5-chlorobenzo [d]thiazol-2-amine in the presence of KCN and acidic medium have been prepared and characterized by elemental chemical analysis (CHNS), molar conductance, magnetic susceptibility measurements, 1H-NMR spectra, FTIR electronic spectral studies and Atomic Absorption Technique. The FTIR spectral data suggest the involvement of amino and acetonitrile nitrogen in coordination to central metal ion. On the basis of spectral studies, an octahedral geometry has been assigned for the divalent transition metal complexes.


Keywords: 2- 2-hydroxy phenyl -2-N-amino 4-chloro-benzothiazol-2-yl acetonitrile, bidentate, divalent, transition metals


Edition: Volume 3 Issue 11, November 2014,


Pages: 3059 - 3064


How to Download this Article?

You Need to Register Your Email Address Before You Can Download the Article PDF


How to Cite this Article?

Mohammed H. A. Al-Amery, "Synthesis and Characterization of New Complexes of 2- (2-Hydroxy Phenyl)-2-N-Amino (4-Chloro-Benzothiazol-2-Yl) Acetonitrile Ligand with Some Divalent Transition Metal Ions", International Journal of Science and Research (IJSR), Volume 3 Issue 11, November 2014, pp. 3059-3064, https://www.ijsr.net/get_abstract.php?paper_id=SUB1461

Similar Articles with Keyword 'bidentate'

Downloads: 125

Research Paper, Chemistry, United Kingdom, Volume 4 Issue 1, January 2015

Pages: 1527 - 1529

Antibacterial Studies of Leucine Complexes of Fe (III) and Cu (II)

K. Asemave [3] | B. A. Anhwange | T. J. Anom

Share this Article

Downloads: 1 | Weekly Hits: ⮙1 | Monthly Hits: ⮙1

Research Paper, Chemistry, India, Volume 13 Issue 2, February 2024

Pages: 766 - 769

Synthesis and Characterization of Coordination polymers of Bis-(mercaptoacatamido) - Butanedioane Dihydrazone

A. D. Bansod

Share this Article
Top