International Journal of Science and Research (IJSR)

International Journal of Science and Research (IJSR)
Call for Papers | Fully Refereed | Open Access | Double Blind Peer Reviewed

ISSN: 2319-7064


Downloads: 128

Research Paper | Chemistry | Iraq | Volume 6 Issue 11, November 2017


Complexes with New Schiff base (N, N`Z, N`, NZ)-N,N-(5,5-dimethylcyclo hexane-1,3-diylidene) dibenzothiazol-2-amine Synthesis, Spectral, Thermal and Theoretical Studies

Abbas Ali Salih Al-Hamdani [2] | Hussaein J. Muhmmah | Waleed M. Sarhan


Abstract: t The synthesis of new bidentate Schiff base (N, N`Z, N`, NZ) -N, N- (5, 5-dimethylcyclo hexane-1, 3-diylidene) dibenzothiazol-2-amine (L), from condensation of 5, 5-Dimethyl-cyclohexane-1, 3-dione with Benzothiazol-2-ylamine. Synthesis of complexes with from reaction of Schiff base and metal ions [Co (II), Ni (II), Cu (II), Zn (II), Cd (II) and Hg (II)] are reported. The structures of new ligand, mode of bonding and overall geometry of the complexes were determined through 1H-NMR UV-Vis, Mass and FT-IR spectral studies, TGA curve, magnetic moment measurements, elemental microanalyses (C. H. N. S. O. ), chloride containing, Atomic absorption and conductance. These studies revealed tetrahedral geometries for all complexes. Complex formation studies via molar ratio and continuous variation methods in DMF solution were consistent to those found in the solid complexes with a ratio of (M L) as (1 1). Hyper Chem-8 program has been used to predict structural geometries of compounds in gas phase, the heat of formation, binding energy, total energy and electronic energy) and dipole moment at 298 K.


Keywords: Benzothiazol-2-ylamine Theoretical Studies, Spectral studies, Schiff base Complexes


Edition: Volume 6 Issue 11, November 2017,


Pages: 803 - 809


How to Download this Article?

You Need to Register Your Email Address Before You Can Download the Article PDF


How to Cite this Article?

Abbas Ali Salih Al-Hamdani, Hussaein J. Muhmmah, Waleed M. Sarhan, "Complexes with New Schiff base (N, N`Z, N`, NZ)-N,N-(5,5-dimethylcyclo hexane-1,3-diylidene) dibenzothiazol-2-amine Synthesis, Spectral, Thermal and Theoretical Studies", International Journal of Science and Research (IJSR), Volume 6 Issue 11, November 2017, pp. 803-809, https://www.ijsr.net/get_abstract.php?paper_id=ART20178047

Similar Articles with Keyword 'Spectral studies'

Downloads: 1 | Weekly Hits: ⮙1 | Monthly Hits: ⮙1

Research Paper, Chemistry, India, Volume 13 Issue 2, February 2024

Pages: 766 - 769

Synthesis and Characterization of Coordination polymers of Bis-(mercaptoacatamido) - Butanedioane Dihydrazone

A. D. Bansod

Share this Article

Downloads: 7 | Monthly Hits: ⮙1

Research Paper, Chemistry, Nigeria, Volume 11 Issue 3, March 2022

Pages: 625 - 630

Spectral Studies and Antimicrobial Activities of Novel Synthesized Oxovanadium (IV) Complexes with Steroid Ligands

Uchenna P. Ogodo | Olufunso O. Abosede

Share this Article
Top