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Research Paper | Chemistry | India | Volume 3 Issue 5, May 2014
Thermodynamic Approach for Oxidation of p-Chloro Benzoic Acid Hydrazide by Thallium (III) in Acidic Medium - A Kinetic and Mechanistic Study
A. S. Varale [2] | Y. S. Varale [2]
Abstract: The kinetics of oxidation of benzoic and p-Chloro benzoic acid hydrazide by Thaliium (III) in a mixture of perchloric and hydrochloric acid medium at a constant ionic strength has been planned to study iodometrically. TlIII + Hydrazide Complex Kc Complex TlI + Intermediate kl TlIII+Intermediate TlI + Products fast The increase in [H+] and [Cl-] decreases the rate of the reaction. The activation parameters were also determined and a mechanism is predicted.
Keywords: kinetics, Thallium III, Oxidation
Edition: Volume 3 Issue 5, May 2014,
Pages: 1857 - 1859
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