Downloads: 95 | Weekly Hits: ⮙2
Research Paper | Chemistry | Iraq | Volume 4 Issue 7, July 2015
Synthesis, Characterization of Some Metal Complexes With Mixed Ligands Derived from Sulfamethoxazole and 4, 4-dimethyl-2, 2-bipyridyl
Mahasin F. Alias; Maysoon M. Abdul Hassan; Sameaa J. Khammas
Mixed ligand complexes of the 4-amino-N- (5-methylisoxazole-3-yl)-benzene-sulfonamide (L1) as a chelating ligand in presence of the co-ligand 4, 4'-dimethyl-2, 2'-bipyridyl (L2) were prepared by treated with V (IV), Cr (III), Co (II), Ni (II) and Cd (II) ions in alcoholic medium in order to prepare a series of new metal complexes. The complexes were characterized in solid state by using flame atomic absorption, elemental analysis C. H. N. S, FT-IR, UV-Vis Spectroscopy, conductivity and magnetic susceptibility measurements. An octahedral geometry was suggested for CrL1L2 and NiL1L2 complexes and tetrahedral geometry was suggested for CoL1L2, CdL1L2 complexes, while VL1L2 complex has a square pyramidal. The ligand L1, with the metal ions, clearly behaves as a bidentate through the O, N atoms of sulfonylamid group for all the prepared complexes except Ni (II), which ligand treated as a tridentate chelate through the O, N atoms of sulfonylamid group and N atom of amine group, while L2 behaves as a bidentate ligand through two N atom. Conductivity measurements have shown that all the prepared complexes are ionic. Different bonding and structural behaviors were revealed throughout the study of coordination chemistry of the newly prepared metal complexes. The nature of bonding between the metal ion and the donor atoms of the ligands were demonstrated by calculating of the ligand field parameters which were calculated using suitable Tanaba-Sugano diagrams.
Keywords: Sulfamethoxazole, 4, 4'-dimethyl-2, 2'-bipyridyl, Chelating agent, Spectroscopy
Edition: Volume 4 Issue 7, July 2015
Pages: 2337 - 2342
How to Cite this Article?
Mahasin F. Alias; Maysoon M. Abdul Hassan; Sameaa J. Khammas, "Synthesis, Characterization of Some Metal Complexes With Mixed Ligands Derived from Sulfamethoxazole and 4, 4-dimethyl-2, 2-bipyridyl", International Journal of Science and Research (IJSR), https://www.ijsr.net/search_index_results_paperid.php?id=SUB156627, Volume 4 Issue 7, July 2015, 2337 - 2342
Similar Articles with Keyword '4'
Downloads: 127
Research Paper, Chemistry, India, Volume 5 Issue 5, May 2016
Pages: 2066 - 2070Comparative Study of the Antiurolithiatic Activity of Plant Hydroalcoholic Extract of Argemone mexicana, Cissus javana DC and Garcinia pendunculata
O. Ibopishak Singh, A. Bimola Devi
Downloads: 152
Research Paper, Chemistry, Iraq, Volume 7 Issue 8, August 2018
Pages: 39 - 43p-Aminobenzoic Acid as a New Reagent in Spectrophotometric Determination of Salbutamol Sulphate Via Oxidative Coupling Reaction
Nabeel S. Othman Ali M. Asaad
Similar Articles with Keyword 'Chelating agent'
Downloads: 112
Research Paper, Chemistry, Iraq, Volume 6 Issue 8, August 2017
Pages: 2211 - 2214Spectrophotometric and Thermodynamic Studies of Complexation between Catechin and Some of Transition Metals (II)
Ahmed.N Abd, Elham.M Al-Rufaie, Haider.N Hussein
Downloads: 115
Research Paper, Chemistry, Tunisia, Volume 3 Issue 8, August 2014
Pages: 1945 - 1951Determination of Aluminium with 8-Hydroxyquinoline in the Hemodialysis Waters By Liquid Chromatography of Reversed Phase Polarity
Soumaya GHARBI, Bassem JAMOUSSI
Similar Articles with Keyword 'Spectroscopy'
Downloads: 132 | Monthly Hits: ⮙1
Research Paper, Chemistry, Libya, Volume 6 Issue 10, October 2017
Pages: 494 - 497The Effect of pH and Ionic Strength on the Bulk and Interfacial Properties of Starches
Fateh Eltaboni, Abedelqader Imragaa, Hamida Altajury, Hana Alshelmany, Nora Omar, Ranya Ali
Downloads: 0
Research Paper, Chemistry, India, Volume 10 Issue 7, July 2021
Pages: 1362 - 1364Phototungstic Acid Catalyzed Synthesis of Benzo (h) Chromen-2-one3-methyl Carboxylate and Study its Anti-Inflammatory Property
Anna R. Anthony