Research Paper | Chemistry | United Kingdom | Volume 4 Issue 1, January 2015
Antibacterial Studies of Leucine Complexes of Fe (III) and Cu (II)
K. Asemave, B. A. Anhwange, T. J. Anom
Fe (III) and Cu (II) complexes of leucine were synthesised and characterized. The inhibition strengths of these complexes against some bacteria were evaluated. It was found that the max of the complexes were at 670 nm and 650 nm for Cu-leu and Fe-leu respectively. There was an observed red shift between the max of the metal salts and their complexes. This shift is a strong implication of coordination. The conductance of the complexes in water was 330.00 S and 17.60 S for Cu-leu and Fe-leu respectively. The IR frequencies of the leucine due to +NH3 group found at 1533.46 cm-1 and 2616.53 cm-1 disappeared in the complexes, indicating coordination through +NH3. Also the peaks for s (COO-) in the leucine was 1389.76cm-1. This band was decreased to 1379.15 cm-1 and 1385.90 cm-1 for Cu-leu and Fe-leu respectively. These changes also portend coordination of the leucine to these metal ions via carboxylate. Again, IR bands for Cu-leu and Fe-leu at 3241.48 cm1 and 3372.66 cm1 are firm evidence of the presence of coordinated water molecules in the complexes. The Fe and Cu ions are thus coordinated to the ligand via carboxylate (COO-) and H3N+ groups in a bidentate fashion. Octahedral and square pyramidal geometry were proposed for the Fe-leu and Cu-leu complexes respectively. The results of the antimicrobial screening by agar diffusion with these amino acids complexes showed increased antibacterial activities when compared to their salts.
Keywords: Antibacterial, Leucine, Complexes, Coordination, Conductance
Edition: Volume 4 Issue 1, January 2015
Pages: 1527 - 1529
How to Cite this Article?
K. Asemave, B. A. Anhwange, T. J. Anom, "Antibacterial Studies of Leucine Complexes of Fe (III) and Cu (II)", International Journal of Science and Research (IJSR), https://www.ijsr.net/search_index_results_paperid.php?id=SUB15491, Volume 4 Issue 1, January 2015, 1527 - 1529
136 PDF Views | 89 PDF Downloads
Click below to Watch Video Lecture of Above Article
Similar Articles with Keyword 'Antibacterial'
Research Paper, Chemistry, United Kingdom, Volume 4 Issue 1, January 2015
Pages: 1527 - 1529Antibacterial Studies of Leucine Complexes of Fe (III) and Cu (II)
K. Asemave, B. A. Anhwange, T. J. Anom
Research Paper, Chemistry, Iraq, Volume 5 Issue 5, May 2016
Pages: 1787 - 1793Synthesis, Characterization and Antimicrobial Activity Studies of Mixed-1,10-phenanthroline-Mn(II),Co(II), Cu(II), Ni(II) and Hg(II) Complexes with Schiff Base[2,2-(1Z,1Z)-(biphenyl-4,4-diylbis(azan-1-yl-1-ylidene))bis(methan-1-yl-1-ylidene)diphenol]
Rehab K. Al-Shemary, Ali M. A. Al-Khazraji, Alaa Fadhil sulaiman Sajid M. Lateef
Research Paper, Chemistry, India, Volume 9 Issue 3, March 2020
Pages: 1472 - 1474Synthesis and Antibacterial Activity of Complexes of 2, 2-Dipyridyldisulphide with ND(III) and TB(III) Metals
Kavita L. Kendre, Girish Pande
Research Paper, Chemistry, Iraq, Volume 6 Issue 8, August 2017
Pages: 1461 - 1467Design ? Syntheses, Characterization and Evaluation Antimicrobial Activity for Some azobenzen-p, p-disubstituted with (3, O), (3, N-) substitute, (3, H) -quinazolin-4-one-2yl and 4-substituted quinazolin-2yl moieties
Zakaria H. Aiube, Zainab A. Jabarah
Research Paper, Chemistry, Libya, Volume 3 Issue 9, September 2014
Pages: 1677 - 1680Preliminary Phytochemical and Antibacterial Studies of Olea europaea and Polygonum maritimum Libyan Plants
Salem Edrah, Ashok Kumar
Similar Articles with Keyword 'Leucine'
Research Paper, Chemistry, United Kingdom, Volume 4 Issue 1, January 2015
Pages: 1527 - 1529Antibacterial Studies of Leucine Complexes of Fe (III) and Cu (II)
K. Asemave, B. A. Anhwange, T. J. Anom
Research Paper, Chemistry, Iraq, Volume 5 Issue 4, April 2016
Pages: 536 - 542Synthesis and Characterization of New 1, 3, 4-Thiadiazoles Substituted with Imidazolidine Moiety
Qasim Mehdi Ismael, Faez Abdul-Hussien Alrammahi, Zeid Hassan Abood
Similar Articles with Keyword 'Complexes'
Research Paper, Chemistry, United Kingdom, Volume 4 Issue 1, January 2015
Pages: 1527 - 1529Antibacterial Studies of Leucine Complexes of Fe (III) and Cu (II)
K. Asemave, B. A. Anhwange, T. J. Anom
Research Paper, Chemistry, Iraq, Volume 4 Issue 3, March 2015
Pages: 2222 - 2226Spectrophotometric Method for Determination and Biological Activity of Trace Amount of Cd(II) by bis(2-((pyridin-2-ylimino)methyl)phenyl)-4,4-(diazene-1,2-diyl)dibenzoate
Mohanad Hazim Naji Halboos
Research Paper, Chemistry, Iraq, Volume 5 Issue 5, May 2016
Pages: 1787 - 1793Synthesis, Characterization and Antimicrobial Activity Studies of Mixed-1,10-phenanthroline-Mn(II),Co(II), Cu(II), Ni(II) and Hg(II) Complexes with Schiff Base[2,2-(1Z,1Z)-(biphenyl-4,4-diylbis(azan-1-yl-1-ylidene))bis(methan-1-yl-1-ylidene)diphenol]
Rehab K. Al-Shemary, Ali M. A. Al-Khazraji, Alaa Fadhil sulaiman Sajid M. Lateef
Research Paper, Chemistry, India, Volume 9 Issue 3, March 2020
Pages: 1472 - 1474Synthesis and Antibacterial Activity of Complexes of 2, 2-Dipyridyldisulphide with ND(III) and TB(III) Metals
Kavita L. Kendre, Girish Pande
Research Paper, Chemistry, Iraq, Volume 4 Issue 7, July 2015
Pages: 2337 - 2342Synthesis, Characterization of Some Metal Complexes With Mixed Ligands Derived from Sulfamethoxazole and 4, 4-dimethyl-2, 2-bipyridyl
Mahasin F. Alias; Maysoon M. Abdul Hassan; Sameaa J. Khammas
Similar Articles with Keyword 'Coordination'
Research Paper, Chemistry, United Kingdom, Volume 4 Issue 1, January 2015
Pages: 1527 - 1529Antibacterial Studies of Leucine Complexes of Fe (III) and Cu (II)
K. Asemave, B. A. Anhwange, T. J. Anom
Research Paper, Chemistry, Iraq, Volume 4 Issue 7, July 2015
Pages: 2337 - 2342Synthesis, Characterization of Some Metal Complexes With Mixed Ligands Derived from Sulfamethoxazole and 4, 4-dimethyl-2, 2-bipyridyl
Mahasin F. Alias; Maysoon M. Abdul Hassan; Sameaa J. Khammas
Research Paper, Chemistry, India, Volume 3 Issue 3, March 2014
Pages: 77 - 80Synthesis and Characterization of Complexes of Co (II) and Hg (II) with 2- Methoxy-2- Thioquinaldine Anilide
Abha Sinha
Research Paper, Chemistry, India, Volume 4 Issue 2, February 2015
Pages: 1351 - 1358Speciation Studies of Dimethyltin (IV) and Trimethyltin (IV) - Carboxylates Systems
Meena Devi, Renu Nair Ahuja
Research Paper, Chemistry, Iraq, Volume 3 Issue 11, November 2014
Pages: 3059 - 3064Synthesis and Characterization of New Complexes of 2- (2-Hydroxy Phenyl)-2-N-Amino (4-Chloro-Benzothiazol-2-Yl) Acetonitrile Ligand with Some Divalent Transition Metal Ions
Mohammed H. A. Al-Amery
Similar Articles with Keyword 'Conductance'
Research Paper, Chemistry, United Kingdom, Volume 4 Issue 1, January 2015
Pages: 1527 - 1529Antibacterial Studies of Leucine Complexes of Fe (III) and Cu (II)
K. Asemave, B. A. Anhwange, T. J. Anom
Research Paper, Chemistry, India, Volume 9 Issue 3, March 2020
Pages: 1472 - 1474Synthesis and Antibacterial Activity of Complexes of 2, 2-Dipyridyldisulphide with ND(III) and TB(III) Metals
Kavita L. Kendre, Girish Pande
Research Paper, Chemistry, Iraq, Volume 3 Issue 12, December 2014
Pages: 2670 - 2677Synthesis & Spectroscopic Study of Ni (??), Cu (??), Co (???), Cr (???) &Fe (???) Complexes with 1, 3, 4-thiadiazol
Fatimah Abdul Hasan Nader AL-Ghazzawi
Research Paper, Chemistry, India, Volume 9 Issue 4, April 2020
Pages: 890 - 893A Study of Metal Complexes of (E)-N-{(2-hydroxynaphthalen-1-yl) methylene} Furan-2-Carbohydrazide
Dr. Neelam Kumari
Research Paper, Chemistry, India, Volume 5 Issue 10, October 2016
Pages: 1488 - 1493Synthesis, Spectral Studies and Antimicrobial Screening of 18-Membered Macrocyclic Complexes of Mn(III) and Fe(III)
Sangeeta Lamba, Mithlesh Agrawal, Swati Bugalia