Synthesis of Some Novel Surfactants Based On Di-Oleamide and Evaluation of Their Performance as Corrosion Inhibitors for X-70 Undersweet and Sourconditions
International Journal of Science and Research (IJSR)

International Journal of Science and Research (IJSR)
www.ijsr.net | Open Access | Fully Refereed | Peer Reviewed International Journal

ISSN: 2319-7064


Amazon Sale


Research Paper | Chemistry | Egypt | Volume 4 Issue 5, May 2015

Synthesis of Some Novel Surfactants Based On Di-Oleamide and Evaluation of Their Performance as Corrosion Inhibitors for X-70 Undersweet and Sourconditions

M. A. Migahed, A. M. Al-Sabagh, E. S. Gad, A. H. Halawa, H. M. Abd EL-Bary

The main objective of this work was to examine the corrosion inhibition ability of three novel surfactant molecules synthesized from N,N'- ( azanediylbis ( ethane-2,1-diyl )) dioleamide which named (I, II and III). Their chemical structures were confirmed using FTIR and 1HNMR spectroscopic methods. The surface active properties of the synthesized surfactants were calculated from surface tension measurements. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques were used to evaluate their performance as corrosion inhibitors for X-70 type tubing steel in deep oil wells formation water under sweet and sour environment at 25oC. Polarization curves showed that by increasing the inhibitor concentration the corrosion current density was decreased, and the prepared surfactants acted as mixed type inhibitors. But the cathodic effect is more pronounced. Data obtained from EIS technique were analyzed to model the corrosion inhibition process through equivalent circuit (EC). Quantum chemical calculations based on ab initio method were performed on I, II and III. The molecular structural parameters, such as the frontier molecular orbital energy HOMO (highest occupied molecular orbital) and LUMO (lowest unoccupied molecular orbital), and the fraction of electrons (-N) transfer from inhibitor to carbon steel surface were calculated and discussed. Finally, the nature of the formed protective film was analyzed by SEM and EDX techniques. The results showed that the selected surfactants have good efficiencies as corrosion inhibitors for tubing steel in deep oil wells formation water under sweet and sour conditions.

Keywords: Surfactants based on di-Oleamide, corrosion inhibitors, deep oil wells formation water, X-70 tubing steel, potentiodynamic polarization, EIS, SEM, EDX

Edition: Volume 4 Issue 5, May 2015

Pages: 1035 - 1050

Share this Article

How to Cite this Article?

M. A. Migahed, A. M. Al-Sabagh, E. S. Gad, A. H. Halawa, H. M. Abd EL-Bary, "Synthesis of Some Novel Surfactants Based On Di-Oleamide and Evaluation of Their Performance as Corrosion Inhibitors for X-70 Undersweet and Sourconditions", International Journal of Science and Research (IJSR), https://www.ijsr.net/search_index_results_paperid.php?id=SUB154153, Volume 4 Issue 5, May 2015, 1035 - 1050

56 PDF Views | 50 PDF Downloads

Download Article PDF


Amazon Sale


Similar Articles with Keyword 'Surfactants based on di-Oleamide'

Research Paper, Chemistry, Egypt, Volume 4 Issue 5, May 2015

Pages: 1035 - 1050

Synthesis of Some Novel Surfactants Based On Di-Oleamide and Evaluation of Their Performance as Corrosion Inhibitors for X-70 Undersweet and Sourconditions

M. A. Migahed, A. M. Al-Sabagh, E. S. Gad, A. H. Halawa, H. M. Abd EL-Bary

Share this Article

Research Paper, Chemistry, Egypt, Volume 4 Issue 5, May 2015

Pages: 535 - 547

Synthesis, Characterization of Some Surfactants Based on Di-Oleamide and Evaluation of Their Efficiency as Corrosion Inhibitors for Oil Wells Tubing Steel under CO2 and H2Senvironment

M.A. Migahed, A.M. Al-Sabagh, E.S. Gad, F. Abd El-Hay, H. M. Abd EL-Bary

Share this Article

Similar Articles with Keyword 'corrosion inhibitors'

Research Paper, Chemistry, Egypt, Volume 3 Issue 12, December 2014

Pages: 1317 - 1322

Polyaniline Nanoparticles Prepared by Micro-Emulsion Polymerization for Corrosion Inhibition of Carbon Steel in 1M HCl

Rania E. Morsi, E.A. Khamis

Share this Article

Research Paper, Chemistry, Egypt, Volume 4 Issue 5, May 2015

Pages: 1035 - 1050

Synthesis of Some Novel Surfactants Based On Di-Oleamide and Evaluation of Their Performance as Corrosion Inhibitors for X-70 Undersweet and Sourconditions

M. A. Migahed, A. M. Al-Sabagh, E. S. Gad, A. H. Halawa, H. M. Abd EL-Bary

Share this Article

Research Paper, Chemistry, India, Volume 4 Issue 1, January 2015

Pages: 1645 - 1650

Synthesis, Characterization and Corrosion Behavior of Isomers of Conducting Poly?Toluidine on Mild Steel in Acid Medium

G.Madhusudhana, R. Jaya Santhi

Share this Article

Review Papers, Chemistry, India, Volume 5 Issue 4, April 2016

Pages: 671 - 677

Drugs as Corrosion Inhibitors: A Review

R. K. Pathak, Pratiksha Mishra

Share this Article

Research Paper, Chemistry, Egypt, Volume 4 Issue 5, May 2015

Pages: 535 - 547

Synthesis, Characterization of Some Surfactants Based on Di-Oleamide and Evaluation of Their Efficiency as Corrosion Inhibitors for Oil Wells Tubing Steel under CO2 and H2Senvironment

M.A. Migahed, A.M. Al-Sabagh, E.S. Gad, F. Abd El-Hay, H. M. Abd EL-Bary

Share this Article

Similar Articles with Keyword 'deep oil wells formation water'

Research Paper, Chemistry, Egypt, Volume 4 Issue 5, May 2015

Pages: 1035 - 1050

Synthesis of Some Novel Surfactants Based On Di-Oleamide and Evaluation of Their Performance as Corrosion Inhibitors for X-70 Undersweet and Sourconditions

M. A. Migahed, A. M. Al-Sabagh, E. S. Gad, A. H. Halawa, H. M. Abd EL-Bary

Share this Article

Research Paper, Chemistry, Egypt, Volume 4 Issue 5, May 2015

Pages: 535 - 547

Synthesis, Characterization of Some Surfactants Based on Di-Oleamide and Evaluation of Their Efficiency as Corrosion Inhibitors for Oil Wells Tubing Steel under CO2 and H2Senvironment

M.A. Migahed, A.M. Al-Sabagh, E.S. Gad, F. Abd El-Hay, H. M. Abd EL-Bary

Share this Article

Similar Articles with Keyword 'potentiodynamic polarization'

Research Paper, Chemistry, Egypt, Volume 4 Issue 5, May 2015

Pages: 1035 - 1050

Synthesis of Some Novel Surfactants Based On Di-Oleamide and Evaluation of Their Performance as Corrosion Inhibitors for X-70 Undersweet and Sourconditions

M. A. Migahed, A. M. Al-Sabagh, E. S. Gad, A. H. Halawa, H. M. Abd EL-Bary

Share this Article

Review Papers, Chemistry, India, Volume 5 Issue 4, April 2016

Pages: 671 - 677

Drugs as Corrosion Inhibitors: A Review

R. K. Pathak, Pratiksha Mishra

Share this Article

Research Paper, Chemistry, Egypt, Volume 4 Issue 5, May 2015

Pages: 535 - 547

Synthesis, Characterization of Some Surfactants Based on Di-Oleamide and Evaluation of Their Efficiency as Corrosion Inhibitors for Oil Wells Tubing Steel under CO2 and H2Senvironment

M.A. Migahed, A.M. Al-Sabagh, E.S. Gad, F. Abd El-Hay, H. M. Abd EL-Bary

Share this Article

Research Paper, Chemistry, India, Volume 5 Issue 4, April 2016

Pages: 1852 - 1857

Corrosion Inhibition of Chlorine Substituted Piperidin?4? One On Mild Steel in Sulphuric Acid Medium

Rathidevi.K, Jalajaa.D

Share this Article

Research Paper, Chemistry, Iraq, Volume 6 Issue 7, July 2017

Pages: 1656 - 1669

Combined Quantum Mechanical and Electrochemical Study of New Isatin Derivative as Corrosion Inhibitor for Carbon Steel in 3.5 % NaCl

Rehab Majed Kubba, Dhuha Abdul-Kareem Challoob, Suaad Mohammed Hussen

Share this Article

Similar Articles with Keyword 'EIS'

Research Paper, Chemistry, India, Volume 3 Issue 7, July 2014

Pages: 1516 - 1518

Antibacterial Activity of Terpenoidal Fractions from Anogeissus against Community Acquired Infections

Dr. Subhadra Rajpoot, Dr. Preeti Singh

Share this Article

Research Paper, Chemistry, Egypt, Volume 4 Issue 5, May 2015

Pages: 1035 - 1050

Synthesis of Some Novel Surfactants Based On Di-Oleamide and Evaluation of Their Performance as Corrosion Inhibitors for X-70 Undersweet and Sourconditions

M. A. Migahed, A. M. Al-Sabagh, E. S. Gad, A. H. Halawa, H. M. Abd EL-Bary

Share this Article

Research Paper, Chemistry, India, Volume 4 Issue 1, January 2015

Pages: 1645 - 1650

Synthesis, Characterization and Corrosion Behavior of Isomers of Conducting Poly?Toluidine on Mild Steel in Acid Medium

G.Madhusudhana, R. Jaya Santhi

Share this Article

Research Paper, Chemistry, Egypt, Volume 4 Issue 5, May 2015

Pages: 535 - 547

Synthesis, Characterization of Some Surfactants Based on Di-Oleamide and Evaluation of Their Efficiency as Corrosion Inhibitors for Oil Wells Tubing Steel under CO2 and H2Senvironment

M.A. Migahed, A.M. Al-Sabagh, E.S. Gad, F. Abd El-Hay, H. M. Abd EL-Bary

Share this Article

Research Paper, Chemistry, India, Volume 5 Issue 4, April 2016

Pages: 1852 - 1857

Corrosion Inhibition of Chlorine Substituted Piperidin?4? One On Mild Steel in Sulphuric Acid Medium

Rathidevi.K, Jalajaa.D

Share this Article

Similar Articles with Keyword 'SEM'

Review Papers, Chemistry, United Kingdom, Volume 4 Issue 12, December 2015

Pages: 2133 - 2135

African Shea Butter as a Staple and Renewable Bioproduct

Kaana Asemave, Tabitha Amarkasev Asemave

Share this Article

Research Paper, Chemistry, India, Volume 4 Issue 2, February 2015

Pages: 2040 - 2044

Kinetics and Equilibrium Studies on the Removal of Direct Blue Dye Using Activated Carbon from Phyllanthus Reticulatus (Black Honey)

G. Kavitha, V. Venkateswaran

Share this Article

Research Paper, Chemistry, India, Volume 3 Issue 9, September 2014

Pages: 2399 - 2403

Eco Friendly Egg Shell Mediated Aldol Condensation

T. Clarina, Beyo Melin Valentina, Dr. V. Rama

Share this Article

Research Paper, Chemistry, India, Volume 3 Issue 9, September 2014

Pages: 1539 - 1544

Synthesis, Characterization and Application of Nanoparticles of Sulfide of Zn2+, Cd2+ and Hg2+ ions by Using Biogenic and Chemical Route

C. P. Gupta, Lakshmi, N. Srivastava, S. Shukla, A. K.Yadav

Share this Article

Research Paper, Chemistry, Iraq, Volume 3 Issue 10, October 2014

Pages: 1920 - 1925

New design and Modulating of Spectroinc 20 to the Home- Made Semi-Automated Chemiluminescence Flow Injection System and Determination of Hydrogen Peroxide in Pharmaceutical Formulations

K. H. Al Sowdani, M. Abdulkadhim. H

Share this Article

Similar Articles with Keyword 'EDX'

Research Paper, Chemistry, Egypt, Volume 4 Issue 5, May 2015

Pages: 1035 - 1050

Synthesis of Some Novel Surfactants Based On Di-Oleamide and Evaluation of Their Performance as Corrosion Inhibitors for X-70 Undersweet and Sourconditions

M. A. Migahed, A. M. Al-Sabagh, E. S. Gad, A. H. Halawa, H. M. Abd EL-Bary

Share this Article

Research Paper, Chemistry, India, Volume 4 Issue 1, January 2015

Pages: 1933 - 1939

A Comparative Study on Catalytic Activity of Solid Acid Catalysts towards Microwave Assisted Synthesis of Coumarin Derivatives

Uma Chudasama, Shrinivas Ghodke

Share this Article

Research Paper, Chemistry, Iraq, Volume 3 Issue 11, November 2014

Pages: 2133 - 2138

Modification of the Photocatalytic Activity of Zinc Oxide by Doping Silver

Amjed M. Odeh, Ahmed S. Ferhod, Abbas J. Lafta

Share this Article

Research Paper, Chemistry, India, Volume 2 Issue 7, July 2013

Pages: 157 - 162

A Novel Nano Structured LaCaxCr1-xO3-δ for Humidity Sensors

B. Avila Josephine, V. Jeseentharani, V. Mary Teresita, S. Arul Antony

Share this Article

Research Paper, Chemistry, Iraq, Volume 4 Issue 6, June 2015

Pages: 3022 - 3027

Synthesis of MWCNT Functionalized SiO2 Thin Film for Biosensor Application

Ahmed Mishaal Mohammed

Share this Article
Top