Synthesis and Characterization of New Complexes of 2- (2-Hydroxy Phenyl)-2-N-Amino (4-Chloro-Benzothiazol-2-Yl) Acetonitrile Ligand with Some Divalent Transition Metal Ions
International Journal of Science and Research (IJSR)

International Journal of Science and Research (IJSR)
www.ijsr.net | Open Access | Fully Refereed | Peer Reviewed International Journal

ISSN: 2319-7064

Research Paper | Chemistry | Iraq | Volume 3 Issue 11, November 2014

Synthesis and Characterization of New Complexes of 2- (2-Hydroxy Phenyl)-2-N-Amino (4-Chloro-Benzothiazol-2-Yl) Acetonitrile Ligand with Some Divalent Transition Metal Ions

Mohammed H. A. Al-Amery

A series of metal complexes of some divalent transition metal ions [MnII, CoII, NiII, CuII, ZnII, CdII, HgII] having the general composition [ML2Cl2].nH2O with bidentate 2- (2-hydroxy phenyl) -2-N-amino (4-chloro- benzothiazol-2-yl) acetonitrile ligand which was prepared from 2-hydroxy-benzaldehyde and 5-chlorobenzo[d]thiazol-2-amine in the presence of KCN and acidic medium have been prepared and characterized by elemental chemical analysis (CHNS), molar conductance, magnetic susceptibility measurements, 1H-NMR spectra, FTIR electronic spectral studies and Atomic Absorption Technique. The FTIR spectral data suggest the involvement of amino and acetonitrile nitrogen in coordination to central metal ion. On the basis of spectral studies, an octahedral geometry has been assigned for the divalent transition metal complexes.

Keywords: 2- 2-hydroxy phenyl -2-N-amino 4-chloro-benzothiazol-2-yl acetonitrile, bidentate, divalent, transition metals

Edition: Volume 3 Issue 11, November 2014

Pages: 3059 - 3064

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Mohammed H. A. Al-Amery, "Synthesis and Characterization of New Complexes of 2- (2-Hydroxy Phenyl)-2-N-Amino (4-Chloro-Benzothiazol-2-Yl) Acetonitrile Ligand with Some Divalent Transition Metal Ions", International Journal of Science and Research (IJSR), https://www.ijsr.net/search_index_results_paperid.php?id=SUB1461, Volume 3 Issue 11, November 2014, 3059 - 3064

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