Kinetics of oxidation of m-Toluidine by Potassium Dichromate in Absence and Presence of CTAB
International Journal of Science and Research (IJSR)

International Journal of Science and Research (IJSR)
www.ijsr.net | Open Access | Fully Refereed | Peer Reviewed International Journal

ISSN: 2319-7064

Research Paper | Chemistry | India | Volume 9 Issue 12, December 2020

Kinetics of oxidation of m-Toluidine by Potassium Dichromate in Absence and Presence of CTAB

Ritu Singh

The Oxidation of m-toluidine by Potassium dichromate has been studied both spectrophotometrically (640nm) and iodometrically in aqueous nitric acid medium in absence and presence of micelle (CTAB). The reaction is said to follow consecutive reaction mechanism. The reaction shows substrate inhibition at low H+ concentration. Oxidation proceeds by two routes and both routes give the colored product. Kinetic parameters are calculated in absence of surfactant but could not be calculated in presence of surfactant because absorbance after showing maxima showed marginal dip indicating decomposition of colored product. Reaction is retarded in presence of micelle. Suitable mechanism is proposed. The rate constants, equilibrium constants and kinetic parameters are calculated.

Keywords: Kinetics, Oxidation, Catalyst, m-toluidine, Micelle

Edition: Volume 9 Issue 12, December 2020

Pages: 935 - 940

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How to Cite this Article?

Ritu Singh, "Kinetics of oxidation of m-Toluidine by Potassium Dichromate in Absence and Presence of CTAB", International Journal of Science and Research (IJSR), https://www.ijsr.net/search_index_results_paperid.php?id=SR201110085826, Volume 9 Issue 12, December 2020, 935 - 940

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