Research Paper | Chemistry | India | Volume 9 Issue 11, November 2020
Sterically Hindered Organoantimony Compounds of TRIS (α-NAPHTHYL) Antimony (III)(α-C10H7)nSbX3-n(n=1,2) & TRIS (α-Naphthyl) Antimony (V) ( α-C10H7)nSbX5-n (n=2,3,4) Derivatives
Neeraj Kumar Verma
Several new hitherto unreported penta-coordinate tris ( & alpha; -naphthyl) - antimony (iii) & antimony (v) halothiocyanato, Interpseudohalide, Interhalogen of the general formulas ( & alpha; -C10H7) nSbX3-n and ( & alpha; -C10H7) nSb5-n (n=1, 2 where OOCR = C6H5CONHCH2COO-, C6H4 (OH) COO-, C6H5C2H4COO-, (C6H5) 2 (OH) C. COO, etc. X=halogens) have been prepared by the metathesis reaction of ( & alpha; -C10H7) nSbX3-n with the appropriate metals salts of the carboxylic acid. The halothiocyanate derivatives were also obtained by the addition of the tris ( & alpha; -naphthyl) -antimony (iii) & antimony (v). The newly synthesized compounds have been characterised by conventional methods. The failure to replace the second halogen atom in ( & alpha; -C10H7) nSbX3-n may be attributed to steric hindrance offered by the naphthyl groups bound to antimony as well as the bulky nature of the organic ligand.
Keywords: Tris &alpha, -naphthyl - antimony iii & antimony v, Halothiocyanato, Interpseudohalide, Interhalogen, Carboxylate
Edition: Volume 9 Issue 11, November 2020
Pages: 258 - 263
How to Cite this Article?
Neeraj Kumar Verma, "Sterically Hindered Organoantimony Compounds of TRIS (α-NAPHTHYL) Antimony (III)(α-C10H7)nSbX3-n(n=1,2) & TRIS (α-Naphthyl) Antimony (V) ( α-C10H7)nSbX5-n (n=2,3,4) Derivatives", International Journal of Science and Research (IJSR), https://www.ijsr.net/search_index_results_paperid.php?id=SR201102224954, Volume 9 Issue 11, November 2020, 258 - 263
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