Kinetics and Mechanism of the Selective Oxidation of Benzoic and Isonicotinic Acid Hydrazides to their Corresponding Acids by Thallium (III) in Aqueous 1, 4-Dioxane Medium
International Journal of Science and Research (IJSR)

International Journal of Science and Research (IJSR)
www.ijsr.net | Open Access | Fully Refereed | Peer Reviewed International Journal

ISSN: 2319-7064

Downloads: 123 | Weekly Hits: ⮙5

Research Paper | Chemistry | India | Volume 3 Issue 11, November 2014

Kinetics and Mechanism of the Selective Oxidation of Benzoic and Isonicotinic Acid Hydrazides to their Corresponding Acids by Thallium (III) in Aqueous 1, 4-Dioxane Medium

Dr. Amit Shrikant Varale

Kinetics of the oxidation of benzoic and isonicotinic acid hydrazides has been studied by Thallium (III) in a mixture of perchloric and hydrochloric acid media at a constant ionic strength in 1, 4-dioxane-water medium, iodometrically. The reaction showed pseudo-first order. The reaction was found to fractional with [Hydrazide] and unity with [oxidant]. The reaction failed to induce the polymerisation of added acrylonitrile and this rules out the involvement of any radical intermediate in the reaction. The increase in [H+] and [Cl-] decreases the rate of the reaction. The increase in ionic strength does not affect the rate of reaction. The effect of temperature was studied at four different temperatures ranging from 150C to 300C. The order of reactivity among the studied hydrazides is isonicotinic acid hydrazide > Benzoic acid hydrazide. The Michealis - Menten plots of 1/kobs versus 1/ [Hydrazide] were linear with an intercept in support of the complex formation. Thermodynamic parameters were determined and a suitable mechanism is proposed in accordance with the obtained results.

Keywords: Thallium III, benzoic and isonicotinic acid hydrazides, Oxidation, Kinetics, Mechanism

Edition: Volume 3 Issue 11, November 2014

Pages: 249 - 251

Share this Article

How to Cite this Article?

Dr. Amit Shrikant Varale, "Kinetics and Mechanism of the Selective Oxidation of Benzoic and Isonicotinic Acid Hydrazides to their Corresponding Acids by Thallium (III) in Aqueous 1, 4-Dioxane Medium", International Journal of Science and Research (IJSR), https://www.ijsr.net/search_index_results_paperid.php?id=OCT14820, Volume 3 Issue 11, November 2014, 249 - 251

Enter Your Email Address




Similar Articles with Keyword 'Thallium III'

Downloads: 105

Research Paper, Chemistry, India, Volume 3 Issue 5, May 2014

Pages: 1865 - 1867

Study of Various Factors on Oxidation of p-Nitro Benzoic Acid Hydrazide - A Kinetic and Mechanistic Approach

A. S. Varale, Y. S. Varale

Share this Article

Downloads: 111

Research Paper, Chemistry, India, Volume 3 Issue 5, May 2014

Pages: 1857 - 1859

Thermodynamic Approach for Oxidation of p-Chloro Benzoic Acid Hydrazide by Thallium (III) in Acidic Medium - A Kinetic and Mechanistic Study

A. S. Varale, Y. S. Varale

Share this Article

Downloads: 123 | Weekly Hits: ⮙5

Research Paper, Chemistry, India, Volume 3 Issue 11, November 2014

Pages: 249 - 251

Kinetics and Mechanism of the Selective Oxidation of Benzoic and Isonicotinic Acid Hydrazides to their Corresponding Acids by Thallium (III) in Aqueous 1, 4-Dioxane Medium

Dr. Amit Shrikant Varale

Share this Article

Downloads: 145 | Weekly Hits: ⮙3

Research Paper, Chemistry, India, Volume 6 Issue 6, June 2017

Pages: 948 - 952

Kinetics and Mechanistic Approach of the Selective Oxidation of n-Butyric Acid Hydrazide to the Corresponding Acid by Thallium (III) in 1, 4-Dioxane Medium

Dr. Amit Shrikant Varale

Share this Article

Similar Articles with Keyword 'Oxidation'

Downloads: 48 | Monthly Hits: ⮙4

Research Paper, Chemistry, India, Volume 10 Issue 3, March 2021

Pages: 411 - 413

Toluene Oxidation on LaVO3 Perovskite Catalyst

H. S. Goswami, Shveta Acharya

Share this Article

Downloads: 72

Research Paper, Chemistry, India, Volume 9 Issue 12, December 2020

Pages: 935 - 940

Kinetics of oxidation of m-Toluidine by Potassium Dichromate in Absence and Presence of CTAB

Ritu Singh

Share this Article

Downloads: 100 | Monthly Hits: ⮙12

Research Paper, Chemistry, India, Volume 3 Issue 7, July 2014

Pages: 1303 - 1305

Oxidase Studies of Substituted Catechols using Copper (II) Complex of Bis (2-benzimidazolylmethyl) ether

Kalpa Mandal

Share this Article

Downloads: 102

Research Paper, Chemistry, Tunisia, Volume 4 Issue 5, May 2015

Pages: 2643 - 2649

Mineralization of Synthetic and Industrial Food Effluent Containing Acid Red18 by Electro-Fenton Process using a Graphite-Felt Cathode

Nouha Ben Hafaiedh, Nizar Bellakhal

Share this Article

Downloads: 103

Research Paper, Chemistry, Egypt, Volume 3 Issue 12, December 2014

Pages: 1317 - 1322

Polyaniline Nanoparticles Prepared by Micro-Emulsion Polymerization for Corrosion Inhibition of Carbon Steel in 1M HCl

Rania E. Morsi, E.A. Khamis

Share this Article

Similar Articles with Keyword 'Kinetics'

Downloads: 117

Research Paper, Chemistry, India, Volume 3 Issue 6, June 2014

Pages: 2047 - 2050

Removal of Lead from Aqueous Solution Using Black Liquor - A Pulp Mill Waste

Anuja Agarwal, Babita Kapil

Share this Article

Downloads: 1

Research Paper, Chemistry, India, Volume 4 Issue 2, February 2015

Pages: 2040 - 2044

Kinetics and Equilibrium Studies on the Removal of Direct Blue Dye Using Activated Carbon from Phyllanthus Reticulatus (Black Honey)

G. Kavitha, V. Venkateswaran

Share this Article

Downloads: 34

Research Paper, Chemistry, India, Volume 10 Issue 2, February 2021

Pages: 1543 - 1548

Removal of Ni (II) from Aqueous Solution by Fly Ash, Kinetic and Equilibrium Studies

Pragya Khandelwal, Pooja Soni, Shweta Saxena

Share this Article

Downloads: 45

Research Paper, Chemistry, Morocco, Volume 4 Issue 8, August 2015

Pages: 538 - 540

Moisture Transfer in Wood Packaging below the Fiber Saturation Point

Kawtar EL MOKHTARI; M'hammed EL KOUALI; Mohammed TALBI; Driss BORIKY; Abdlhak EL BROUZI

Share this Article

Downloads: 72

Research Paper, Chemistry, India, Volume 9 Issue 12, December 2020

Pages: 935 - 940

Kinetics of oxidation of m-Toluidine by Potassium Dichromate in Absence and Presence of CTAB

Ritu Singh

Share this Article

Similar Articles with Keyword 'Mechanism'

Downloads: 72

Research Paper, Chemistry, India, Volume 9 Issue 12, December 2020

Pages: 935 - 940

Kinetics of oxidation of m-Toluidine by Potassium Dichromate in Absence and Presence of CTAB

Ritu Singh

Share this Article

Downloads: 100

Research Paper, Chemistry, India, Volume 6 Issue 12, December 2017

Pages: 1552 - 1555

Mixed Ligand Complexes of Alkali Metal Salts of Some Organic Acids with O-Hydroxyacetophenone Phenylhydrazone ?2, 4 ? Dinitrophenyl Hydrazone

Shahnawaz Mahmood

Share this Article

Downloads: 104

Research Paper, Chemistry, Nigeria, Volume 4 Issue 8, August 2015

Pages: 1106 - 1111

The Formulation of Dispersion Media for Some Organotin Compounds

Stephen G. Yiase

Share this Article

Downloads: 105

Research Paper, Chemistry, India, Volume 3 Issue 5, May 2014

Pages: 1865 - 1867

Study of Various Factors on Oxidation of p-Nitro Benzoic Acid Hydrazide - A Kinetic and Mechanistic Approach

A. S. Varale, Y. S. Varale

Share this Article

Downloads: 107 | Weekly Hits: ⮙1

Research Paper, Chemistry, India, Volume 5 Issue 1, January 2016

Pages: 1358 - 1363

Molecularity, Bond-Fission and Reaction Mechanism in the Acid Hydrolysis of p-Propoxy Aniline Phosphate Diester Via Conjugate Acid Species

Dr. Amit Chaudhary

Share this Article



Top