International Journal of Science and Research (IJSR)

International Journal of Science and Research (IJSR)
www.ijsr.net | Most Trusted Research Journal Since Year 2012

ISSN: 2319-7064



Research Paper | Chemistry Science | India | Volume 3 Issue 10, October 2014

Rapid Kinetics of Chlorination of Regioisomers of Nitrophenol by Molecular Chlorine in Aqueous Medium Using Rotating Platinum Electrode (RPE)

S. L. Bonde, R. P. Bhadane, V. T. Dangat, T. M. Sukul

The rapid kinetics of chlorination of isomers of nitrophenol in aqueous solution by molecular chlorine in KNO3 as supporting electrolyte has been studied using the rotating platinum electrode (RPE). The specific reaction rate (k), energy of activation (Ea), free energy change of activation (G*), enthalpy change of activation (H*), entropy change of activation (S*) were evaluated. The reaction was found to be rapid and of the second order. The rapidity of the reaction necessitated the use of a special technique RPE. The diffusion current of unreacted chlorine in the reaction was measured. Thus, the present work provides the quantitative verification of the reactivity of the electrophile in the reaction.

Keywords: Rapid Chlorination, Rotating Platinum Electrode, Kinetics

Edition: Volume 3 Issue 10, October 2014

Pages: 797 - 801


How to Cite this Article?

S. L. Bonde, R. P. Bhadane, V. T. Dangat, T. M. Sukul, "Rapid Kinetics of Chlorination of Regioisomers of Nitrophenol by Molecular Chlorine in Aqueous Medium Using Rotating Platinum Electrode (RPE)", International Journal of Science and Research (IJSR), https://www.ijsr.net/search_index_results_paperid.php?id=OCT1470, Volume 3 Issue 10, October 2014, 797 - 801

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