Research Paper | Chemistry | Nigeria | Volume 8 Issue 2, February 2019
Spectrophotometric Determination of Tin (IV) in Solder and Brass Using 6-[(E)-(1,5-Dimethyl-3-Oxo-2-Phenyl-2,3-Dihydro-1h-Pyrazol-4-Yl)Diazenyl]-1h-Indole-2,3-Dione
Chinyere Evans Eledalachi, Okenwa Jude Chukwudi, Ukoha Pius Oziri
In the present paper, a new method is proposed for the spectrophotometric determination of tin (IV) in solder and brass. The ligand, 6-[ (E) - (1, 5-dimethyl-3-oxo-2-phenyl-2, 3-dihydro-1H-pyrazol-4-yl) diazenyl]-1H-indole-2, 3-dione was synthesized by coupling diazotized 1-phenyl-2, 3-dimethyl-4-aminopyrazole-5-one and 1H-indole-2, 3-dione. It formed coloured complex with Sn (IV). The ligand and complex were characterized via UV, IR and NMR spectroscopy. The analytical data show that Sn (IV) formed complex, with 2: 1 metal-ligand stoichiometry when reacted with the ligand respectively. Sn (IV) was determined spectrophotometrically by measuring the absorbance at 421.4 nm. Beers law was valid between 0.34-2.81 ppm, with calibration and analytical sensitivities of 0.068 and 67.00 ppm respectively. Very few elements were found to interfere in the method. The method is quite simple and useful; its applicability has been tested by the analysis of solder and brass.
Keywords: 4-aminoantipyrine, isatin, spectrophotometry, tin IV, alloys
Edition: Volume 8 Issue 2, February 2019
Pages: 413 - 418
How to Cite this Article?
Chinyere Evans Eledalachi, Okenwa Jude Chukwudi, Ukoha Pius Oziri, "Spectrophotometric Determination of Tin (IV) in Solder and Brass Using 6-[(E)-(1,5-Dimethyl-3-Oxo-2-Phenyl-2,3-Dihydro-1h-Pyrazol-4-Yl)Diazenyl]-1h-Indole-2,3-Dione", International Journal of Science and Research (IJSR), https://www.ijsr.net/search_index_results_paperid.php?id=ART20194853, Volume 8 Issue 2, February 2019, 413 - 418
200 PDF Views | 133 PDF Downloads
Similar Articles with Keyword '4-aminoantipyrine'
Research Paper, Chemistry, India, Volume 4 Issue 10, October 2015
Pages: 1603 - 1611Experimental and Theoretical Vibrational Spectroscopic Study of Schiff base Derived from 4-Amino Antipyrine- A Quantum Chemical Study
Kishor Arora, Anu Parmar
Research Paper, Chemistry, Iraq, Volume 4 Issue 6, June 2015
Pages: 504 - 508Thermal Analysis of Different Pyrazolone Azo Derivative and Their Complexes with Pd(II), Ni(II) and Ag(I)
Aayad Ammar Syhood, Hussain J Mohammed
Research Paper, Chemistry, Nigeria, Volume 8 Issue 2, February 2019
Pages: 413 - 418Spectrophotometric Determination of Tin (IV) in Solder and Brass Using 6-[(E)-(1,5-Dimethyl-3-Oxo-2-Phenyl-2,3-Dihydro-1h-Pyrazol-4-Yl)Diazenyl]-1h-Indole-2,3-Dione
Chinyere Evans Eledalachi, Okenwa Jude Chukwudi, Ukoha Pius Oziri
Similar Articles with Keyword 'isatin'
Research Paper, Chemistry, Nigeria, Volume 4 Issue 9, September 2015
Pages: 2084 - 2088Synthesis, Characterization and Antimicrobial Studies of Mn(II), Ni(II) and Cu(II) Mixed Ligand Complexes Derived from Isatinphenylhydrazone and Nitrogen / Sulphurmonodentate Ligands
Iniama G. E, Olanrele O. S., Iorkpiligh T. I.
Research Paper, Chemistry, Iraq, Volume 4 Issue 8, August 2015
Pages: 2083 - 2089Synthesis of Isatine Derivatives Considering Pfitzinger Reaction Part I
Prof. Dr. Mohammad Mahdi Saleh, Marwa Ibrahim Khaleel
Research Paper, Chemistry, Iraq, Volume 6 Issue 7, July 2017
Pages: 1656 - 1669Combined Quantum Mechanical and Electrochemical Study of New Isatin Derivative as Corrosion Inhibitor for Carbon Steel in 3.5 % NaCl
Rehab Majed Kubba, Dhuha Abdul-Kareem Challoob, Suaad Mohammed Hussen
Research Paper, Chemistry, India, Volume 3 Issue 6, June 2014
Pages: 424 - 428Monoamine Oxidase Inhibitory and Anticonvulsant Activities of Some Substituted Isatin Semicarbazones
Ashok Kumar, S. B. Singh, Ismail M. Awheda
Research Paper, Chemistry, Iraq, Volume 6 Issue 10, October 2017
Pages: 1040 - 1044Synthesis and Characterization of Some New Polymers for Isatin
Zaynab Hussein Fadel, Sameaa J. Khammas, Wasan Abdul Razzaq Mahmood
Similar Articles with Keyword 'spectrophotometry'
Research Paper, Chemistry, India, Volume 3 Issue 7, July 2014
Pages: 1546 - 1550Sensitive Spectrophotometric Determination of Chlorpyrifos in Different Environmental and Biological Samples
Vindhiya Patel, Manish Kumar Rai, Prashant Mundeja, Joyce Rai
Research Paper, Chemistry, India, Volume 3 Issue 6, June 2014
Pages: 900 - 903Development and Validation of New Analytical Methods for the Determination of Endoxan in Pharmaceutical Formulations by UV-Visible Spectrophotometry
Swapna.G, Manoj Kumar
Research Paper, Chemistry, India, Volume 4 Issue 5, May 2015
Pages: 1026 - 1031Spectrophotometric Method for the Determination of Furazolidone in Pharmaceutical Formulations and Human Blood Samples with MBTH
B. Ramachandra, N. Venkatasubba Naidu
Research Paper, Chemistry, Egypt, Volume 3 Issue 11, November 2014
Pages: 2781 - 2785Morphological and Visible Spectrophotometric Analysis of Copper, Iron, Manganese and Lead Interactions with Extract Chlorophyll
Amr S Ismail
Research Paper, Chemistry, India, Volume 3 Issue 6, June 2014
Pages: 202 - 205A New Spectrophotometric Determination of Endosulfan and Its Application
Kalpana Wani, M. K Rai, Raisa Khatoon
Similar Articles with Keyword 'tin IV'
Research Paper, Chemistry, India, Volume 4 Issue 2, February 2015
Pages: 1351 - 1358Speciation Studies of Dimethyltin (IV) and Trimethyltin (IV) - Carboxylates Systems
Meena Devi, Renu Nair Ahuja
Research Paper, Chemistry, India, Volume 4 Issue 4, April 2015
Pages: 2895 - 2899Potentiometric Studies on Binary Complexes of Catecholic Compounds with Organotin (IV) Cations
Meena Devi, Renu Nair Ahuja
Research Paper, Chemistry, India, Volume 4 Issue 1, January 2015
Pages: 1933 - 1939A Comparative Study on Catalytic Activity of Solid Acid Catalysts towards Microwave Assisted Synthesis of Coumarin Derivatives
Uma Chudasama, Shrinivas Ghodke
Research Paper, Chemistry, India, Volume 4 Issue 12, December 2015
Pages: 1298 - 1302Equilibrium Studies on Interaction of Organotin (IV) Moieties with N-O Donor Ligands
Pratibha Paliwal Bhatele, Seema Yadav Kumari
Research Paper, Chemistry, Nigeria, Volume 8 Issue 2, February 2019
Pages: 413 - 418Spectrophotometric Determination of Tin (IV) in Solder and Brass Using 6-[(E)-(1,5-Dimethyl-3-Oxo-2-Phenyl-2,3-Dihydro-1h-Pyrazol-4-Yl)Diazenyl]-1h-Indole-2,3-Dione
Chinyere Evans Eledalachi, Okenwa Jude Chukwudi, Ukoha Pius Oziri
Similar Articles with Keyword 'alloys'
Research Paper, Chemistry, Morocco, Volume 3 Issue 6, June 2014
Pages: 2157 - 2161Structure and Thermodynamic of Zr(Cr1-x Fex)2 Alloys Under Hydrogen Pressure
M.Boulghallat, A. Jouaiti, L.Lallaam, A. Barroug, D. Dafir
Research Paper, Chemistry, India, Volume 5 Issue 8, August 2016
Pages: 1034 - 1039Long Term Corrosion Investigation of Cold Rolled High Nitrogen Steels in Simulated Body Fluid
Mohd Talha, O. P. Sinha
Research Paper, Chemistry, India, Volume 4 Issue 8, August 2015
Pages: 549 - 553Electrochemical Deposition and Characterization of Zinc-Cobalt
Neha Deshmukh, R. K. Pathak
Research Paper, Chemistry, Morocco, Volume 3 Issue 7, July 2014
Pages: 1470 - 1474Mechanism and Kinetics of Hydrogen Diffusion in Some Zr(Cr1-x Fex)2 Laves phase
M. Boulghallat, A. Jouaiti, L. Lallam
Review Papers, Chemistry, India, Volume 5 Issue 12, December 2016
Pages: 1463 - 1467Electrodeposition of Metal Alloys (Ni, Zn and Fe) and their Characterization: A Review
R. K. Pathak, Mukta Rani Bhawsar