Unique Polymerization and New Smart Material of Eugenol-Based Helical Polymers
International Journal of Science and Research (IJSR)

International Journal of Science and Research (IJSR)
www.ijsr.net | Open Access | Fully Refereed | Peer Reviewed International Journal

ISSN: 2319-7064


Amazon Sale


Research Paper | Chemistry | Indonesia | Volume 7 Issue 11, November 2018

Unique Polymerization and New Smart Material of Eugenol-Based Helical Polymers

Erwin Abdul Rahim

The series of eugenolbased helical polymers were synthesized. The polymerization of 14 with Rh catalyst gave the corresponding polyacetylene [poly (1) poly (4) ] in different yield and a molecular weight ranging from 5, 000-11, 000. Splitting of methoxy (OCH3) group which is indicated of conformational isomerization cis-trans like amide group of eugenol part affected to polymerization yield and Mn. Polymerization monomer 1 and 2 is not easy, but polymerization of 3 and 4 gives high yield and Mn of the polymer. These polymers were soluble in common organic solvent and shown stable helical structure. Eugenol-based optically active helical polyacetylene catalysts as a new smart material have been synthesized. The new smart material was observed when measured in 1H NMR; proton NH moves when cursor move to the peak of NH. This is because of spontan crystallization and isomerization of methoxy group of crystal chiral of eugenol part. These properties make this catalyst as a new smart material.

Keywords: Conformational isomerization, Methoxy group, Eugenol-Based Polymers, Rh

Edition: Volume 7 Issue 11, November 2018

Pages: 990 - 996

Share this Article

How to Cite this Article?

Erwin Abdul Rahim, "Unique Polymerization and New Smart Material of Eugenol-Based Helical Polymers", International Journal of Science and Research (IJSR), https://www.ijsr.net/search_index_results_paperid.php?id=ART20192899, Volume 7 Issue 11, November 2018, 990 - 996

122 PDF Views | 72 PDF Downloads

Download Article PDF


Amazon Sale


Similar Articles with Keyword 'Rh'

Research Paper, Chemistry, Kenya, Volume 7 Issue 2, February 2018

Pages: 1283 - 1288

Fixed Column Removal of Lead (II) Ions from Industrial Effluent using Pig Bone Char, Rice-Husks Ash and Water Hyacinth Composite Adsorbent

Genson Murithi; Karanja wa Thiong'o; Wachira Muthengia

Share this Article

Research Paper, Chemistry, India, Volume 3 Issue 10, October 2014

Pages: 730 - 738

Evaluation of the Antifungal Activity of the Potent Fraction of Hexane Extract Obtained from the bark of Acacia Nilotica

Satya Prakash Rai, Manisha S. Prasad, Khushboo Singh

Share this Article

Research Paper, Chemistry, India, Volume 4 Issue 6, June 2015

Pages: 1532 - 1535

Rp-Hplc Method Development and Validation for the Analysis of Pharmaceutical Drugs- 60 % Sodium Lactate

Dr. Bhaskarrav Makwana, Dr. V. G. Patel, Vipalben Patel, Ami Patel

Share this Article

Research Paper, Chemistry, Iraq, Volume 4 Issue 10, October 2015

Pages: 2012 - 2018

Synthesis of New ?-Adrenergic Blocking Agents Having Heterocyclic Moiety with Expected Activity

Ekhlass T. Soore, Ahlam J. Qasir

Share this Article

Research Paper, Chemistry, India, Volume 5 Issue 4, April 2016

Pages: 1203 - 1208

Kinetic Study of the Hydrolysis of p-Propoxy Aniline Phosphate Triester

Dr. Amit Chaudhary

Share this Article
Top