Metal Complexes as Ligands: Binuclear Alkali Metal and Trinuclear Alkaline Earth Metal Complexes with Nickel (II) and Copper (II) Metal Complexes of isonitrosoacetylacetone
International Journal of Science and Research (IJSR)

International Journal of Science and Research (IJSR)
www.ijsr.net | Open Access | Fully Refereed | Peer Reviewed International Journal

ISSN: 2319-7064

Research Paper | Chemistry | India | Volume 6 Issue 2, February 2017

Metal Complexes as Ligands: Binuclear Alkali Metal and Trinuclear Alkaline Earth Metal Complexes with Nickel (II) and Copper (II) Metal Complexes of isonitrosoacetylacetone

Om Prakash Gupta

In the present study we have synthesized new binuclear complexes of alkali metal salts and trinuclear complexes of alkaline earth metal salts with interaction of stable metal chelates of isonitrosoacetylacetone of Ni (II) & Cu (II) having general formula [Ma (INAA) 2. MbL] and [Ma (INAA) 2.MbX] for alkali metal addcuts [Ma (INAA) 2. MbL2] and[Ma (INAA) 2.MbX2] for alkaline earth metal adducts, where Ma=Ni (II) or Cu (II) and Mb =Li+, Na+, K+ or Mg++, INAA= deprotonated isonitrosoacetylacetone, L=deprotonated 1-nitroso-2-naphthol or 8-hydroxyquinoline and, X= ClO-4 or SCN-. The IR spectral studies suggests that the Ni (II) & Cu (II) metal chelats act as ligand and coordination towards alkali metal salts and alkaline earth metal salts takes place through oxygen atom of bonded ketonic oxygen. The diffuse reflectance electronic spectra and magnetic moment values of the metal chelates and binuclear& trinuclear complexes with alkali metal and alkaline earth metal salts indicates the change in geometry during oxygen bridged complex formation

Keywords: isonitrosoacetylacetone, 1-nitroso-2-naphthol, 8-hydroxyqunoline, Metal complexes as ligands

Edition: Volume 6 Issue 2, February 2017

Pages: 1365 - 1370

Share this Article

How to Cite this Article?

Om Prakash Gupta, "Metal Complexes as Ligands: Binuclear Alkali Metal and Trinuclear Alkaline Earth Metal Complexes with Nickel (II) and Copper (II) Metal Complexes of isonitrosoacetylacetone", International Journal of Science and Research (IJSR), https://www.ijsr.net/search_index_results_paperid.php?id=ART2017973, Volume 6 Issue 2, February 2017, 1365 - 1370

112 PDF Views | 93 PDF Downloads

Download Article PDF



Similar Articles with Keyword '1-nitroso-2-naphthol'

Research Paper, Chemistry, India, Volume 6 Issue 2, February 2017

Pages: 1365 - 1370

Metal Complexes as Ligands: Binuclear Alkali Metal and Trinuclear Alkaline Earth Metal Complexes with Nickel (II) and Copper (II) Metal Complexes of isonitrosoacetylacetone

Om Prakash Gupta

Share this Article

Research Paper, Chemistry, India, Volume 5 Issue 8, August 2016

Pages: 1492 - 1496

Metal Complexes as ligands: Trinuclear Alkali Metal Complexes with Nickel(II) and Copper(II) Metal Complexes of Violuric Acid (Isonitrosobarbituric Acid)

Om Prakash Gupta

Share this Article

Research Paper, Chemistry, India, Volume 5 Issue 7, July 2016

Pages: 509 - 513

Synthesis and Characterization of Oxygen Bridged Complexes of Metal Chelates of isonitrosopropiophenone with Alkali and Alkaline Earth Metal Salts and Study of their Biological Activitiy

Om Prakash Gupta

Share this Article

Similar Articles with Keyword '8-hydroxyqunoline'

Research Paper, Chemistry, India, Volume 6 Issue 2, February 2017

Pages: 1365 - 1370

Metal Complexes as Ligands: Binuclear Alkali Metal and Trinuclear Alkaline Earth Metal Complexes with Nickel (II) and Copper (II) Metal Complexes of isonitrosoacetylacetone

Om Prakash Gupta

Share this Article

Research Paper, Chemistry, India, Volume 5 Issue 8, August 2016

Pages: 1492 - 1496

Metal Complexes as ligands: Trinuclear Alkali Metal Complexes with Nickel(II) and Copper(II) Metal Complexes of Violuric Acid (Isonitrosobarbituric Acid)

Om Prakash Gupta

Share this Article

Research Paper, Chemistry, India, Volume 5 Issue 7, July 2016

Pages: 509 - 513

Synthesis and Characterization of Oxygen Bridged Complexes of Metal Chelates of isonitrosopropiophenone with Alkali and Alkaline Earth Metal Salts and Study of their Biological Activitiy

Om Prakash Gupta

Share this Article
Top