Kinetics and Mechanistic Approach of the Selective Oxidation of n-Butyric Acid Hydrazide to the Corresponding Acid by Thallium (III) in 1, 4-Dioxane Medium
International Journal of Science and Research (IJSR)

International Journal of Science and Research (IJSR)
www.ijsr.net | Open Access | Fully Refereed | Peer Reviewed International Journal

ISSN: 2319-7064



Downloads: 146

Research Paper | Chemistry | India | Volume 6 Issue 6, June 2017

Kinetics and Mechanistic Approach of the Selective Oxidation of n-Butyric Acid Hydrazide to the Corresponding Acid by Thallium (III) in 1, 4-Dioxane Medium

Dr. Amit Shrikant Varale

The reaction between Thallium (III) and n-Butyric acid hydrazide is carried out in a mixture of perchloric and hydrochloric acid medium. The reaction proceeds through formation of complex with reactant, which decomposes in subsequent steps to give product. Effect of acrylonitrile shows, that there is no formation of free radicals. The increase in [H+] and [Cl-] decreases the rate of the reaction. The increase in ionic strength does not affect the rate of reaction. The effect of temperature was studied at four different temperatures ranging from 150C to 300C. The activation parameters were also determined and a mechanism is predicted.

Keywords: kinetics, Thallium III, Oxidation, n-BuAH

Edition: Volume 6 Issue 6, June 2017

Pages: 948 - 952

Share this Article

How to Cite this Article?

Dr. Amit Shrikant Varale, "Kinetics and Mechanistic Approach of the Selective Oxidation of n-Butyric Acid Hydrazide to the Corresponding Acid by Thallium (III) in 1, 4-Dioxane Medium", International Journal of Science and Research (IJSR), https://www.ijsr.net/search_index_results_paperid.php?id=ART20173745, Volume 6 Issue 6, June 2017, 948 - 952

Enter Your Email Address




Similar Articles with Keyword 'kinetics'

Downloads: 117

Research Paper, Chemistry, India, Volume 3 Issue 6, June 2014

Pages: 2047 - 2050

Removal of Lead from Aqueous Solution Using Black Liquor - A Pulp Mill Waste

Anuja Agarwal, Babita Kapil

Share this Article

Downloads: 1

Research Paper, Chemistry, India, Volume 4 Issue 2, February 2015

Pages: 2040 - 2044

Kinetics and Equilibrium Studies on the Removal of Direct Blue Dye Using Activated Carbon from Phyllanthus Reticulatus (Black Honey)

G. Kavitha, V. Venkateswaran

Share this Article

Similar Articles with Keyword 'Thallium III'

Downloads: 105

Research Paper, Chemistry, India, Volume 3 Issue 5, May 2014

Pages: 1865 - 1867

Study of Various Factors on Oxidation of p-Nitro Benzoic Acid Hydrazide - A Kinetic and Mechanistic Approach

A. S. Varale, Y. S. Varale

Share this Article

Downloads: 111

Research Paper, Chemistry, India, Volume 3 Issue 5, May 2014

Pages: 1857 - 1859

Thermodynamic Approach for Oxidation of p-Chloro Benzoic Acid Hydrazide by Thallium (III) in Acidic Medium - A Kinetic and Mechanistic Study

A. S. Varale, Y. S. Varale

Share this Article

Similar Articles with Keyword 'Oxidation'

Downloads: 48

Research Paper, Chemistry, India, Volume 10 Issue 3, March 2021

Pages: 411 - 413

Toluene Oxidation on LaVO3 Perovskite Catalyst

H. S. Goswami, Shveta Acharya

Share this Article

Downloads: 72

Research Paper, Chemistry, India, Volume 9 Issue 12, December 2020

Pages: 935 - 940

Kinetics of oxidation of m-Toluidine by Potassium Dichromate in Absence and Presence of CTAB

Ritu Singh

Share this Article



Top