Thermodynamic Approach for Oxidation of p-Chloro Benzoic Acid Hydrazide by Thallium (III) in Acidic Medium - A Kinetic and Mechanistic Study
International Journal of Science and Research (IJSR)

International Journal of Science and Research (IJSR)
www.ijsr.net | Open Access | Fully Refereed | Peer Reviewed International Journal

ISSN: 2319-7064

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Research Paper | Chemistry | India | Volume 3 Issue 5, May 2014

Thermodynamic Approach for Oxidation of p-Chloro Benzoic Acid Hydrazide by Thallium (III) in Acidic Medium - A Kinetic and Mechanistic Study

A. S. Varale, Y. S. Varale

The kinetics of oxidation of benzoic and p-Chloro benzoic acid hydrazide by Thaliium (III) in a mixture of perchloric and hydrochloric acid medium at a constant ionic strength has been planned to study iodometrically. TlIII + Hydrazide Complex Kc Complex TlI + Intermediate kl TlIII+Intermediate TlI + Products fast The increase in [H+] and [Cl-] decreases the rate of the reaction. The activation parameters were also determined and a mechanism is predicted.

Keywords: kinetics, Thallium III, Oxidation

Edition: Volume 3 Issue 5, May 2014

Pages: 1857 - 1859

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How to Cite this Article?

A. S. Varale, Y. S. Varale, "Thermodynamic Approach for Oxidation of p-Chloro Benzoic Acid Hydrazide by Thallium (III) in Acidic Medium - A Kinetic and Mechanistic Study ", International Journal of Science and Research (IJSR), https://www.ijsr.net/search_index_results_paperid.php?id=201425, Volume 3 Issue 5, May 2014, 1857 - 1859

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Thermodynamic Approach for Oxidation of p-Chloro Benzoic Acid Hydrazide by Thallium (III) in Acidic Medium - A Kinetic and Mechanistic Study

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