Study of Characterization and Cracking of Sucrose over supported Ni, Mo, Cu/Kieselguhr Catalyst
International Journal of Science and Research (IJSR)

International Journal of Science and Research (IJSR)
www.ijsr.net | Open Access | Fully Refereed | Peer Reviewed International Journal

ISSN: 2319-7064



Downloads: 121 | Monthly Hits: ⮙5

Research Paper | Chemistry | India | Volume 3 Issue 3, March 2014

Study of Characterization and Cracking of Sucrose over supported Ni, Mo, Cu/Kieselguhr Catalyst

Tanuja Srivastava, D. C. Saxena

Sucrose hydrogenolysis is industrially important for the production of glycerol, ethylene glycol and propylene glycol. There is a need of a catalyst providing high product yields under milder reaction conditions. Ni catalyst promoted by Mo and Cu and supported on kieselguhr was synthesized with this purpose. Ni, Mo, Cu/Kieselguhr nano catalyst prepared by simultaneous Co precipitation and digestion method on dilution showed three times higher activity than the reported earlier readings. The catalyst was characterized using the techniques of electron microscopy, X-ray diffraction and magnetic measurements. The maximum yield of glycerol and simultaneously highest conversion of sucrose with water to nickel nitrate ration of 12 was obtained. Present water and nitrates solution ratio reveals that under this condition sucrose may be hydrogenolysis to yields glycerol, ethylene glycol and propylene glycol directly instead of first producing glucose and fructose. Thus the overall picture of the hydrogenolysis of sucrose is quite complex. A large number of consecutive and parallel reactions are involved. Various routes of product formation are shown in fig. The use of suitable catalyst under appropriate conditions may produce desired mixture. Magnetic moments studies have revealed a decrease in the magnetic moment of nickel when dropped with copper. This indicates some electron transfer from copper and molybdenum to 3d band of nickel. Electron microscopy studies indicated a marked change in morphology of the kieselguhr grains. Coprecipitation of the catalyst seems to change the morphology of support particles from sharp edged particles into fibrous state. Transmission electron micrograph of unreduced catalyst shows this fibrous stage. The surface area measurement of the optimum (Ni, Mo, Cu) /kieselguhr catalyst is recorded as 789m2/g.

Keywords: catalyst, nickel, copper, Response Surface Methodology, Glycerol, Hydrogenolysis

Edition: Volume 3 Issue 3, March 2014

Pages: 150 - 156

Share this Article

How to Cite this Article?

Tanuja Srivastava, D. C. Saxena, "Study of Characterization and Cracking of Sucrose over supported Ni, Mo, Cu/Kieselguhr Catalyst", International Journal of Science and Research (IJSR), https://www.ijsr.net/search_index_results_paperid.php?id=20131034, Volume 3 Issue 3, March 2014, 150 - 156

Enter Your Registered Email Address





Similar Articles with Keyword 'catalyst'

Downloads: 47 | Weekly Hits: ⮙1 | Monthly Hits: ⮙20

Research Paper, Chemistry, India, Volume 10 Issue 3, March 2021

Pages: 411 - 413

Toluene Oxidation on LaVO3 Perovskite Catalyst

H. S. Goswami, Shveta Acharya

Share this Article

Downloads: 71 | Weekly Hits: ⮙2 | Monthly Hits: ⮙14

Research Paper, Chemistry, India, Volume 9 Issue 12, December 2020

Pages: 935 - 940

Kinetics of oxidation of m-Toluidine by Potassium Dichromate in Absence and Presence of CTAB

Ritu Singh

Share this Article

Downloads: 83 | Weekly Hits: ⮙4 | Monthly Hits: ⮙20

Dissertation Chapters, Chemistry, India, Volume 9 Issue 12, December 2020

Pages: 1342 - 1351

Experimental Evaluation of Green Approach in Organic Synthesis

Veenu Gupta, Sourabh Gupta

Share this Article

Downloads: 88 | Weekly Hits: ⮙1 | Monthly Hits: ⮙10

Research Paper, Chemistry, India, Volume 3 Issue 9, September 2014

Pages: 2399 - 2403

Eco Friendly Egg Shell Mediated Aldol Condensation

T. Clarina, Beyo Melin Valentina, Dr. V. Rama

Share this Article

Downloads: 99 | Weekly Hits: ⮙3 | Monthly Hits: ⮙10

Research Paper, Chemistry, India, Volume 4 Issue 10, October 2015

Pages: 1205 - 1208

Synthesis of 5, 9b-dihydro-1H-[1,2,4]triazino[5,6-b]indol-3-ol/thiol?s using Sulfamic Acid, A Green and Recyclable Catalyst

Ravi Kumar Ganta, Korrapati. Suresh Babu, K A R S S Prasad, Venkateswara Rao.B

Share this Article

Similar Articles with Keyword 'nickel'

Downloads: 127 | Weekly Hits: ⮙1 | Monthly Hits: ⮙12

Research Paper, Chemistry, Nigeria, Volume 2 Issue 4, April 2013

Pages: 463 - 467

Heavy Metal Analysis of Blends of Methyl Esters Obtained from Four Virgin Tropical Seed Oils

O. G. Igbum, K. Asemave, C. A Nwadinigwe, N. Y. Akaasah

Share this Article

Downloads: 33 | Weekly Hits: ⮙3 | Monthly Hits: ⮙16

Research Paper, Chemistry, India, Volume 10 Issue 2, February 2021

Pages: 1543 - 1548

Removal of Ni (II) from Aqueous Solution by Fly Ash, Kinetic and Equilibrium Studies

Pragya Khandelwal, Pooja Soni, Shweta Saxena

Share this Article

Downloads: 44 | Weekly Hits: ⮙4 | Monthly Hits: ⮙12

Research Paper, Chemistry, India, Volume 10 Issue 1, January 2021

Pages: 1474 - 1479

Synthesis, Spectral Characterization and Antibacterial Activity of Metal Complexes of 2-Methoxy benzaldehyde isonicotinoylhydrazone

E. Lakshmi, T. Krishna, A. Suseelamma, P. Raveendra Reddy

Share this Article

Downloads: 99 | Weekly Hits: ⮙3 | Monthly Hits: ⮙9

Research Paper, Chemistry, India, Volume 4 Issue 9, September 2015

Pages: 1645 - 1651

Cobalt (II), Nickel (II) and Copper (II) Complexes of 5-Methyl-3?[(2?)6?Methyl Benzimidazolyl] Pyrazole

Manika Barar; Arpita Kulshrestha

Share this Article

Downloads: 102 | Weekly Hits: ⮙4

Research Paper, Chemistry, India, Volume 4 Issue 11, November 2015

Pages: 1507 - 1510

Study of Influence of Precursor Decomposition on Oxide and Wet Chemical Methods in Synthesis of Ni?Zn Ferrites

Vikas J. Pissurlekar

Share this Article

Similar Articles with Keyword 'copper'

Downloads: 127 | Weekly Hits: ⮙1 | Monthly Hits: ⮙12

Research Paper, Chemistry, Nigeria, Volume 2 Issue 4, April 2013

Pages: 463 - 467

Heavy Metal Analysis of Blends of Methyl Esters Obtained from Four Virgin Tropical Seed Oils

O. G. Igbum, K. Asemave, C. A Nwadinigwe, N. Y. Akaasah

Share this Article

Downloads: 99 | Weekly Hits: ⮙3 | Monthly Hits: ⮙9

Research Paper, Chemistry, India, Volume 4 Issue 9, September 2015

Pages: 1645 - 1651

Cobalt (II), Nickel (II) and Copper (II) Complexes of 5-Methyl-3?[(2?)6?Methyl Benzimidazolyl] Pyrazole

Manika Barar; Arpita Kulshrestha

Share this Article

Downloads: 100 | Monthly Hits: ⮙12

Research Paper, Chemistry, India, Volume 3 Issue 7, July 2014

Pages: 1303 - 1305

Oxidase Studies of Substituted Catechols using Copper (II) Complex of Bis (2-benzimidazolylmethyl) ether

Kalpa Mandal

Share this Article

Downloads: 102 | Weekly Hits: ⮙1 | Monthly Hits: ⮙12

Research Paper, Chemistry, Egypt, Volume 3 Issue 11, November 2014

Pages: 2781 - 2785

Morphological and Visible Spectrophotometric Analysis of Copper, Iron, Manganese and Lead Interactions with Extract Chlorophyll

Amr S Ismail

Share this Article

Downloads: 103 | Weekly Hits: ⮙3 | Monthly Hits: ⮙11

Research Paper, Chemistry, India, Volume 6 Issue 2, February 2017

Pages: 1365 - 1370

Metal Complexes as Ligands: Binuclear Alkali Metal and Trinuclear Alkaline Earth Metal Complexes with Nickel (II) and Copper (II) Metal Complexes of isonitrosoacetylacetone

Om Prakash Gupta

Share this Article

Similar Articles with Keyword 'Glycerol'

Downloads: 103 | Weekly Hits: ⮙1 | Monthly Hits: ⮙9

Research Paper, Chemistry, India, Volume 3 Issue 10, October 2014

Pages: 580 - 584

Synthesis, Characterization and Some Properties of Glycerol Ester Based Non-Ionic Gemini Surfactant with 1, 2, 7, 8 -Diepoxideoctane as Spacer

Ishwar T. Gawali, Ghayas. A. Usmani

Share this Article

Downloads: 107 | Weekly Hits: ⮙3 | Monthly Hits: ⮙13

Research Paper, Chemistry, India, Volume 3 Issue 11, November 2014

Pages: 794 - 798

Study of Physico-Chemical Properties of Glycerol Ester Based Non-Ionic Gemini Surfactant

Ishwar T. Gawali, Ghayas. A. Usmani

Share this Article

Downloads: 108 | Weekly Hits: ⮙1 | Monthly Hits: ⮙9

Research Paper, Chemistry, Egypt, Volume 3 Issue 12, December 2014

Pages: 1969 - 1975

Esterification Reaction for Novel Synthesis Castor-Based Polyester and Formulation as Base Oil in Synthetic Drilling Fluid

S. Ibrahim

Share this Article

Downloads: 111 | Weekly Hits: ⮙1 | Monthly Hits: ⮙10

Research Paper, Chemistry, India, Volume 4 Issue 8, August 2015

Pages: 1010 - 1014

Enzymatic Synthesis of Micronutrients Rich Diacylglycerol from Rice Bran Oil Fatty Acid Distillate

Sumit Nandi, Rupa Bhattacharyya

Share this Article

Downloads: 121 | Monthly Hits: ⮙5

Research Paper, Chemistry, India, Volume 3 Issue 3, March 2014

Pages: 150 - 156

Study of Characterization and Cracking of Sucrose over supported Ni, Mo, Cu/Kieselguhr Catalyst

Tanuja Srivastava, D. C. Saxena

Share this Article



Top